February 3, 2022
Feature

A New Catalyst for Natural Gas Engines

Palladium oxide catalyst cleans up emissions, enhances water vapor tolerance

Purple and pink catalyst

Catalyst “rafts” of palladium oxide that are held together with single atoms of platinum are effective at cleaning up emissions from natural gas engines.

(Image by Cortland Johnson | Pacific Northwest National Laboratory)

A multi-institution research team has developed a new catalyst that could clean emissions from natural gas-powered vehicles.

Natural gas engines are used for powering some trucks and buses, as well as pumping natural gas into homes for energy use. Natural gas engines are also used in off-road applications such as trucks for mining.

However, catalytic converters to clean exhaust emissions from these engines are less efficient at low temperatures, resulting in emissions of environmentally harmful unburnt methane. Water is also produced by methane combustion, which further impacts the performance of conventional catalysts.

The team’s new catalyst is made up of “rafts” of palladium oxide held together with single atoms of platinum. Not only does the catalyst clean the unburnt methane from the emissions, it enhances water vapor tolerance. This catalyst also shows greater reactivity than other catalysts made of palladium oxide nanoparticles.

The team continues to advance the catalyst and is aiming to commercialize the technology for industry application.

The work was featured in Nature Catalysis. Yong Wang, a Pacific Northwest National Laboratory (PNNL) fellow and the Voiland Distinguished Professor in Chemical Engineering at Washington State University (WSU), was a corresponding author on the paper.

The research was a collaboration among WSU, PNNL, Xiamen University, the University of New Mexico, Fuzhou University, Purdue University, Sandia National Laboratories, ION-TOF GmbH, Tascon GmbH, and Yanshan University.

Wang’s research was supported by the Department of Energy’s Vehicle Technologies Office.

Click here to learn more.

###

About PNNL

Pacific Northwest National Laboratory draws on its distinguishing strengths in chemistry, Earth sciences, biology and data science to advance scientific knowledge and address challenges in sustainable energy and national security. Founded in 1965, PNNL is operated by Battelle for the Department of Energy’s Office of Science, which is the single largest supporter of basic research in the physical sciences in the United States. DOE’s Office of Science is working to address some of the most pressing challenges of our time. For more information, visit https://www.energy.gov/science/. For more information on PNNL, visit PNNL's News Center. Follow us on Twitter, Facebook, LinkedIn and Instagram.