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Textile Processing
Related publications, More applications
Carbon dioxide can be successfully used as a replacement solvent for
water in textile processing. Studies at PNNL have demonstrated that
carbon dioxide can be successfully used in dyeing, applying UV stabilizer
and for the application and removal of "size." Large savings in energy
and reductions in waste generated can be realized by switching to
this "green" solvent.
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| Polymeric "size" applied to cotton/polyester
yarn using liquid CO2 |
Traditional textile processing and production are based on aqueous processing.
The use of water as the carrier solvent for processes, such as slashing
(sizing), desizing, dyeing, and finishing, consumes large quantities
of water, results in large energy consumption for drying and results
in large volumes of wastewater requiring treatment. The development
of a nonaqueous based textile processing represents a radical redesign
of the current process. The advantage of re-engineering the process
from the beginning is that a true "zero discharge" manufacturing operation
can be achieved through the use of an environmentally benign, "green"
solvent. Both liquid and supercritical carbon dioxide can be used
as a replacement solvent for water and exploit its property of existing
as a gas at room temperature.
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| 100% Polyester dyed using supercritical
CO2 |
In studies at PNNL, an elegantly simple system comprising a mixture
of CO2 and dye was used to impregnate polyester
fabric with high loadings of several different color-fast dyes.
In the area of textile sizing/slashing there is an extensive program
at PNNL for using CO2 technology. In textile
sizing/slashing, the elimination of an aqueous process that requires
repeated drying steps and generates a large wastewater stream has
the potential to significantly reduce operating, material, and energy
costs.
For information about supercritical fluid capabilities at PNNL, please contact Clement Yonker, at (509) 372-4748, clem.yonker@pnl.gov.
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