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    Review date: July 24, 2003
    PNNL-SA-27883

     

    Textile Processing
    Related publications, More applications


    Carbon dioxide can be successfully used as a replacement solvent for water in textile processing. Studies at PNNL have demonstrated that carbon dioxide can be successfully used in dyeing, applying UV stabilizer and for the application and removal of "size." Large savings in energy and reductions in waste generated can be realized by switching to this "green" solvent.

    Polymeric "size" applied to cotton/polyester yarn using liquid CO2
    Traditional textile processing and production are based on aqueous processing. The use of water as the carrier solvent for processes, such as slashing (sizing), desizing, dyeing, and finishing, consumes large quantities of water, results in large energy consumption for drying and results in large volumes of wastewater requiring treatment. The development of a nonaqueous based textile processing represents a radical redesign of the current process. The advantage of re-engineering the process from the beginning is that a true "zero discharge" manufacturing operation can be achieved through the use of an environmentally benign, "green" solvent. Both liquid and supercritical carbon dioxide can be used as a replacement solvent for water and exploit its property of existing as a gas at room temperature.
    100% Polyester dyed using supercritical CO2

    In studies at PNNL, an elegantly simple system comprising a mixture of CO2 and dye was used to impregnate polyester fabric with high loadings of several different color-fast dyes. In the area of textile sizing/slashing there is an extensive program at PNNL for using CO2 technology. In textile sizing/slashing, the elimination of an aqueous process that requires repeated drying steps and generates a large wastewater stream has the potential to significantly reduce operating, material, and energy costs.


    For information about supercritical fluid capabilities at PNNL,
    please contact Clement Yonker, at (509) 372-4748, clem.yonker@pnl.gov.