Supercritical Fluid Research at PNNL
At the Pacific Northwest National Laboratory (PNNL) understanding
supercritical fluids (e.g., carbon dioxide,
water, ethane) on a molecular level and their intermolecular interactions
has led to new separations and extraction technologies and novel chemical
synthesis/reaction methodologies. Our on-going research in supercritical
fluids at PNNL is aimed at enhancing efficiency and reducing waste,
providing a basis for improving existing industrial processes.
Supercritical fluids are effective cleaning agents for parts,
printed circuit boards, and garments. Supercritical fluids will be
used as environmentally benign solvents in chemical processes of
the future. The importance of supercritical fluids to hydrothermal
oxidation, organic synthesis, extractions, and separations led to
an emphasis on these research areas at the PNNL. The supercritical
fluids group maintains and continues to develop state-of-the-art
capabilities in the molecular level
investigation of solvation dynamics and in chemical technologies
occurring in supercritical fluid solvents.
Research focuses on the following technology areas:
- Separations and extractions
- Reverse micelles/microemulsions
- Metal complexation
- Membrane/ultrafiltration
- Catalysis/chemical reactions
- Organometallics
- CO2 sequestration
- Parts/garment cleaning
- Materials synthesis
- Rapid expansion of supercritical fluid solvents (RESS)
- Rapid thermal decomposition of precursors in solutions (RTDS)
- Aqueous injection of a supercritical expansion (AISE)
- Supercritical water oxidation/synthesis
- Textile processing
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