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Staff information

Yingge

Yingge Du

Materials Sciences
Scientist
Pacific Northwest National Laboratory
PO Box 999
MSIN: K8-93
Richland, WA 99352

Biography

Dr. Yingge Du is a senior staff scientist in the Materials Group of the Physical and Computational Sciences Directorate. He joined PNNL in 2007 and became a staff member in 2010. He served as technical lead in the acquisition and commissioning of a new state-of-the-art oxide molecular beam epitaxy (MBE) system for the EMSL user facility located at PNNL. His current research focuses on growth and characterization of epitaxial metal oxide films and superlattices for energy conversion and storage applications.

Dr. Du is the recipient of a 2016 DOE Early Career Award. This award will support him to conduct basic research that aims to understand, predict, and ultimately control cation/anion ordering and topotactic phase transitions occurring in transition metal oxide thin films. Achieving so will enable energy materials (e.g., catalysts, electrodes, and electrolytes) with desired functionalities to be designed, synthesized, stabilized, and harnessed for technological benefits.

Research Interests

  • Structure-property relationships in epitaxial oxide thin films
  • Photochemistry and electrochemistry utilizing heteroepitaxial oxide structures
  • Materials, junctions, and devices for next generation computing
  • Development of in situ monitoring and control tools for materials synthesis and processing

Education and Credentials

  • 2007-2009 Postdoctoral Research Fellow, PNNL
  • 2001-2007 Ph.D., Engineering Physics, University of Virginia, Charlottesville, VA
  • 1998-2001 M.E., Engineering Physics, Tsinghua University, Beijing, China
  • 1994-1998 B.S., Engineering Physics, Tsinghua University

Affiliations and Professional Service

  • MRS, AVS, AGU, AAAS

Awards and Recognitions

  • U.S. Department of Energy (DOE) Early Career Award (2016).
  • PNNL Outstanding Performance Award (2008, 2009).
  • Student Fellowship, University of Virginia (2005).
  • Summer Research Institute Research Fellowship, PNNL (2004).
  • TongFang Scholarship, Tsinghua University (2001, 2002).

PNNL Publications

2017

  • Ong PV, Y Du, and P Sushko. 2017. "Low Dimensional Oxygen Vacancy Ordering and Diusion in SrCrO3-d." Journal of Physical Chemistry Letters 8(8):1757-1763.  doi:10.1021/acs.jpclett.7b00355
  • Spurgeon SR, Y Du, and SA Chambers. 2017. "Measurement Error in Atomic-Scale Scanning Transmission Electron Microscopy-Energy-Dispersive X-Ray Spectroscopy (STEM-EDS) Mapping of a Model Oxide Interface." Microscopy and Microanalysis 23(3):513-517.  doi:10.1017/S1431927617000368
  • Chambers SA, Y Du, RB Comes, SR Spurgeon, and P Sushko. 2017. "The effects of core-level broadening in determining band alignment at the epitaxial SrTiO3(001)/p-Ge(001) heterojunction." Applied Physics Letters 110(8):082104.  doi:10.1063/1.4977422
  • Chatterjee S, A Andersen, Y Du, MH Engelhard, GB Hall, TG Levitskaia, WW Lukens, V Shutthanandan, ED Walter, and NM Washton. 2017. Characterization of Non-pertechnetate Species Relevant to the Hanford Tank WastePNNL-26265, Pacific Northwest National Laboratory, Richland, WA. 
  • Du Y, C Li, KHL Zhang, ME McBriarty, SR Spurgeon, HS Mehta, D Wu, and SA Chambers. 2017. "An all-perovskite p-n junction based on transparent conducting p-La1-xSrxCrO3 epitaxial layers." Applied Physics Letters 111(6):063501.  doi:10.1063/1.4997410
  • Engelhard MH, TC Droubay, and Y Du. 2017. "X-Ray photoelectron Spectroscopy Applications." In Encyclopedia of Spectroscopy and Spectrometry, 3rd edition, pp. 716-724.  Academic Press, Oxford, United Kingdom.  doi:10.1016/B978-0-12-409547-2.12102-X
  • Lim Z, K Ahmadi-Majlan, E Grimley, Y Du, ME Bowden, R Moghadam, JM LeBeau, SA Chambers, and J Ngai. 2017. "Structural and electrical properties of single crystalline SrZrO3 epitaxially grown on Ge (001)." Journal of Applied Physics 122(8):Article No. 084102.  doi:10.1063/1.5000142
  • Ngai J, K Ahmadi-Majlan, MJ Moghadam, M Chrysler, D Kumah, F Walker, C Ahn, TC Droubay, Y Du, SA Chambers, ME Bowden, X Shen, and D Su. 2017. "Electrically coupling complex oxides to semiconductors: a route to novel material functionalities." Journal of Materials Research 32(2):249-259.  doi:10.1557/jmr.2016.496
  • Zhang KHL, R Wu, F Tang, W Li, FE Oropeza, L Qiao, VK Lazarov, Y Du, DJ Payne, JL Macmanus-Driscoll, and MG Blamire. 2017. "Electronic structure and band alignment at the NiO and SrTiO3 p-n heterojunctions." ACS Applied Materials & Interfaces 9(31):26549-26555.  doi:10.1021/acsami.7b06025

2016

  • Asmussen RM, CI Pearce, AR Lawter, JJ Neeway, BL Miller, BD Lee, NM Washton, JR Stephenson, RE Clayton, ME Bowden, EC Buck, E Cordova, N Qafoku, and BD Williams. 2016. Getter Incorporation into Cast Stone and Solid State CharacterizationsPNNL-25577 Rev. 0;RPT-SLAW-003 Rev A, Pacific Northwest National Laboratory, Richland, WA. 
  • Du Y, G Li, EW Peterson, J Zhou, X Zhang, R Mu, Z Dohnalek, ME Bowden, I Lyubinetsky, and SA Chambers. 2016. "Iso-oriented monolayer a-MoO3(010) films epitaxially grown on SrTiO3(001)." Nanoscale 8(5):3119-3124.  doi:10.1039/C5NR07745A
  • He Y, M Gu, HY Xiao, L Luo, Y Shao, F Gao, Y Du, SX Mao, and CM Wang. 2016. "Atomistic Conversion Reaction Mechanism of WO3 in Secondary Ion Batteries of Li, Na, and Ca." Angewandte Chemie International Edition 55(21):6244-6247.  doi:10.1002/anie.201601542
  • Levitskaia TG, S Chatterjee, N Pence, J Romero, T Varga, MH Engelhard, Y Du, L Kovarik, BW Arey, ME Bowden, and ED Walter. 2016. "Inorganic Tin Aluminophosphate Nanocomposite for Reductive Separation of Pertechnetate." Environmental Science: Nano 3(2):1003-1013.  doi:10.1039/C6EN00130K
  • Spurgeon SR, Y Du, TC Droubay, A Devaraj, X Sang, P Longo, P Yan, PG Kotula, V Shutthanandan, ME Bowden, JM LeBeau, CM Wang, P Sushko, and SA Chambers. 2016. "Competing Pathways for Nucleation of the Double Perovskite Structure in the Epitaxial Synthesis of La2MnNiO6." Chemistry of Materials 28(11):3814-3822.  doi:10.1021/acs.chemmater.6b00829
  • Wang Z, Y He, M Gu, Y Du, SX Mao, and C Wang. 2016. "Electron Transfer Governed Crystal Transformation of Tungsten Trioxide upon Li Ions Intercalation." ACS Applied Materials & Interfaces 8(37):24567-24572.  doi:10.1021/acsami.6b06581

2015

  • Chambers SA, Y Du, M Gu, TC Droubay, S Hepplestone, and P Sushko. 2015. "Dominance of interface chemistry over the bulk properties in determining the electronic structure of epitaxial metal/perovskite oxide heterojunctions." Chemistry of Materials 27(11):4093-4098.  doi:10.1021/acs.chemmater.5b01118
  • Li G, T Varga, P Yan, Z Wang, CM Wang, SA Chambers, and Y Du. 2015. "Crystallographic Dependence of Photocatalytic Activity of WO3 Thin Films Prepared by Molecular Beam Epitaxy." Physical Chemistry Chemical Physics. PCCP 17(23):15119-15123.  doi:10.1039/c5cp01344e
  • Wang Z, B Liu, E Zhao, K Jin, Y Du, JJ Neeway, JV Ryan, D Hu, H Zhang, M Hong, S Le Guernic, S Thevuthasan, F Wang, and Z Zhu. 2015. "Argon Cluster Sputtering Source for ToF-SIMS Depth Profiling of Insulating Materials: High Sputter Rate and Accurate Interfacial Information." Journal of the American Society for Mass Spectrometry 26(8):1283-1290.  doi:10.1007/s13361-015-1159-1
  • Xu J, F Zhang, B Sun, Y Du, G Li, and W Zhang. 2015. "Enhanced Photocatalytic Property of Cu Doped Sodium Niobate." International Journal of Photoenergy 2015(846121):, doi:10.1155/2015/846121
  • Yoon Y, Y Du, JC Garcia, Z Zhu, Z Wang, NG Petrik, GA Kimmel, Z Dohnalek, MA Henderson, RJ Rousseau, NA Deskins, and I Lyubinetsky. 2015. "Anticorrelation between Surface and Subsurface Point Defects and the Impact on the Redox Chemistry of TiO2(110)." Chemphyschem 16(2):313-321.  doi:10.1002/cphc.201402599
  • Zhang H, Y Du, A Papadogianni, O Bierwagen, S Sallis, LFJ Piper, ME Bowden, V Shutthanandan, P Sushko, and SA Chambers. 2015. "Perovskite Sr-doped LaCrO3 as a new p-type transparent conducting oxide." Advanced Materials 27(35):5191-5195.  doi:10.1002/adma.201501959
  • Zhang H, Y Du, P Sushko, ME Bowden, V Shutthanandan, L Qiao, G Cao, Z Gai, S Sallis, LFJ Piper, and SA Chambers. 2015. "Electronic and magnetic properties of epitaxial perovskite SrCrO3(001)." Journal of Physics: Condensed Matter 27(24):245605.  doi:10.1088/0953-8984/27/24/245605
  • Zhang H, Y Du, P Sushko, ME Bowden, V Shutthanandan, S Sallis, LFJ Piper, and SA Chambers. 2015. "Hole-induced insulator-to-metal transition in La1-xSrxCrO3 epitaxial films." Physical Review. B, Condensed Matter and Materials Physics 91(15):155129.  doi:10.1103/PhysRevB.91.155129

2014

  • Du Y, and SA Chambers. 2014. "Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy." Applied Physics Letters 105(16):163113(1)-163113(5).  doi:10.1063/1.4898638
  • Du Y, H Zhang, T Varga, and SA Chambers. 2014. "Reflection High-Energy Electron Diffraction Beam-Induced Structural and Property Changes on WO3 Thin Films." Applied Physics Letters 105(5):051606.  doi:10.1063/1.4892810
  • Du Y, M Gu, T Varga, CM Wang, ME Bowden, and SA Chambers. 2014. "Strain Accommodation By Facile WO6 Octahedral Distortion and Tilting During WO3 Heteroepitaxy on SrTiO3(001)." ACS Applied Materials & Interfaces 6(16):14253-14258.  doi:10.1021/am5035686
  • Du Y, TC Droubay, AV Liyu, G Li, and SA Chambers. 2014. "Self-corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy." Applied Physics Letters 104(16):Article No. 163110.  doi:10.1063/1.4873544
  • Zhang H, P Sushko, RJ Colby, Y Du, ME Bowden, and SA Chambers. 2014. "Reversible nano-structuring of SrCrO3-d through oxidization and reduction at low temperatures." Nature Communications 5:Artcle No. 4669.  doi:10.1038/ncomms5669

2013

  • Qiao L, H Zhang, ME Bowden, T Varga, V Shutthanandan, RJ Colby, Y Du, BC Kabius, PV Sushko, MD Biegalski, and SA Chambers. 2013. "The Impacts of Cation Stoichiometry and Substrate Surface Quality on Nucleation, Structure, Defect Formation, and Intermixing in Complex Oxide Heteroepitaxy-LaCrO3 on SrTiO3(001)." Advanced Functional Materials 23(23):2953-2963.  doi:10.1002/adfm.201202655
  • Xia Y, K Zhu, TC Kaspar, Y Du, B Birmingham, KT Park, and Z Zhang. 2013. "Atomic Structure of the Anatase TiO2(001) Surface." Journal of Physical Chemistry Letters 4(17):2958-2963.  doi:10.1021/jz401284u

2012

  • Du Y, DJ Kim, TC Kaspar, SE Chamberlin, I Lyubinetsky, and SA Chambers. 2012. "In-situ imaging of the nucleation and growth of epitaxial anatase TiO2(001) films on SrTiO3(001)." Surface Science 606(17-18):1443-1449.  doi:10.1016/j.susc.2012.05.010
  • Du Y, NG Petrik, NA Deskins, Z Wang, MA Henderson, GA Kimmel, and I Lyubinetsky. 2012. "Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared via Carboxylic Acid Adsorption and Photolysis." Physical Chemistry Chemical Physics. PCCP 14(9):3066-3074.  doi:10.1039/C1CP22515D

2011

  • Du Y, DJ Kim, T Varga, Z Wang, J Szanyi, and I Lyubinetsky. 2011. "Formation of single-phase BaO nanoclusters." Thin Solid Films 519(16):5335-5338.  doi:10.1016/j.tsf.2011.02.032

2010

  • Du Y, NA Deskins, Z Zhang, Z Dohnalek, M Dupuis, and I Lyubinetsky. 2010. "Formation of O Adatom Pairs and Charge Transfer upon O-2 Dissociation on Reduced TiO2(110)." Physical Chemistry Chemical Physics. PCCP 12(24):6337-6344. 
  • Du Y, NA Deskins, Z Zhang, Z Dohnalek, M Dupuis, and I Lyubinetsky. 2010. "Water Interactions with Terminal Hydroxyls on TiO2 (110)." Journal of Physical Chemistry C 114(40):17080-17084.  doi:10.1021/jp1036876
  • Lyubinetsky I, NA Deskins, Y Du, EK Vestergaard, DJ Kim, and M Dupuis. 2010. "Adsorption States and Mobility of TMAA Molecules on Reduced TiO2(110) Surface." Physical Chemistry Chemical Physics. PCCP 12(23):5986-5992. 
  • Lyubinetsky I, Y Du, NA Deskins, Z Zhang, Z Dohnalek, and M Dupuis. 2010. "Two Pathways for Water Interaction with Oxygen Adatoms on TiO2(110) Surfaces ." In International Symposium on Atomic Level Characterizations for New Materials and Devices.  Japan Society for the Promotion of Science, Tokyo, Japan. 
  • Wang Z, Y Du, Z Dohnalek, and I Lyubinetsky. 2010. "Direct Observation of Site Specific Molecular Chemisorption of O2 on TiO2 (110)." The Journal of Physical Chemistry Letters 1(24):3524-3529.  doi:10.1021/jz101535f

2009

  • Du Y, NA Deskins, Z Zhang, Z Dohnalek, M Dupuis, and I Lyubinetsky. 2009. "Imaging Consecutive Steps of O2 Reaction with Hydroxylated TiO2(110): Identification of HO2 and Terminal OH Intermediates." Journal of Physical Chemistry C 113(2):666-671.  doi: 10.1021/jp807030n
  • Du Y, NA Deskins, Z Zhang, Z Dohnalek, M Dupuis, and I Lyubinetsky. 2009. "Two Pathways for Water Interaction with Oxygen Adatoms on TiO2(110)." Physical Review Letters 102(9):Art. No. 096102.  doi:10.1103/PhysRevLett.102.096102
  • Ohsawa T, I Lyubinetsky, Y Du, MA Henderson, V Shutthanandan, and SA Chambers. 2009. "Crystallographic Dependence of Visible-light Photoactivity in Epitaxial TiO2-xNx Anatase and Rutile." Physical Review. B, Condensed Matter and Materials Physics 79(8):Article number: 085401.  doi:10.1103/PhysRevB.79.085401
  • Ohsawa T, I Lyubinetsky, Y Du, MA Henderson, V Shutthanandan, and SA Chambers. 2009. "Crystallographic Dependence of Visible-Light Photochemistry in Epitaxial TiO2-xNx Anatase and Rutile." Physical Review. B, Condensed Matter and Materials Physics 79(8):Art. No. 085401. 
  • Petrik NG, Z Zhang, Y Du, Z Dohnalek, I Lyubinetsky, and GA Kimmel. 2009. "Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption." Journal of Physical Chemistry C 113(28):12407-12411.  doi:10.1021/jp901989x
  • Zhang Z, Y Du, NG Petrik, GA Kimmel, I Lyubinetsky, and Z Dohnalek. 2009. "Water as a Catalyst: Imaging Reactions of O-2 with Partially and Fully Hydroxylated TiO2(110) Surfaces." Journal of Physical Chemistry C 113(5):1908-1916. 

2008

  • Du Y, Z Dohnalek, and I Lyubinetsky. 2008. "Transient Mobility of Oxygen Adatoms upon O2 Dissociation on Reduced TiO2 (110)." Journal of Physical Chemistry C 112(7):2649-2653.  doi:10.1021/jp077677u
  • Groves JF, Y Du, I Lyubinetsky, and DR Baer. 2008. "Focused ion beam directed self-assembly (Cu2O on SrTiO3 ): FIB pit and Cu2O nanodot evolution." Superlattices and Microstructures 44(4-5):677-685.  doi:10.1016/j.spmi.2008.01.016
  • Li SC, Z Zhang, D Sheppard, BD Kay, JM White, Y Du, I Lyubinetsky, GA Henkelman, and Z Dohnalek. 2008. "Intrinsic Diffusion of Hydrogen on Rutile TiO2(110)." Journal of the American Chemical Society 130(28):9080-9088.  doi:10.1021/ja8012825

2006

  • Du Y, JF Groves, I Lyubinetsky, and DR Baer. 2006. "Formation of Cu2O Quantum Dots on SrTiO3 (100): Self-Assembly and Directed Self-Assembly." Journal of Applied Physics 100(9):Art. No. 094315.  doi:10.1063/1.2364038
  • Yu Z, CM Wang, Y Du, S Thevuthasan, and I Lyubinetsky. 2006. "Reproducible Tip Fabrication and Cleaning for UHV STM ." Ultramicroscopy 108(9):873-877.  doi:10.1016/j.ultramic.2008.02.010

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