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Staff information

John Linehan

Catalysis Science
Scientist
Pacific Northwest National Laboratory
PO Box 999
MSIN: K2-57
Richland, WA 99352

PNNL Publications

2009

  • Rousseau RJ, GK Schenter, JL Fulton, JC Linehan, MH Engelhard, and T Autrey. 2009. "Defining Active Catalyst Structure and Reaction Pathways from ab Initio Molecular Dynamics and Operando XAFS: Dehydrogenation of Dimethylaminoborane by Rhodium Clusters ." Journal of the American Chemical Society 131(30):10516-10524. 
  • Kathmann SM, VM Parvanov, GK Schenter, AC Stowe, LL Daemen, MA Hartl, JC Linehan, NJ Hess, AJ Karkamkar, and T Autrey. 2009. "Experimental and Computational Studies on Collective Hydrogen Dynamics in Ammonia Borane: Incoherent Inelastic Neutron Scattering." Journal of Chemical Physics 130(2):article no. 024507.  doi:10.1063/1.3042270
  • Neiner D, AJ Karkamkar, JC Linehan, BW Arey, T Autrey, and SM Kauzlarich. 2009. "Promotion of Hydrogen Release from Ammonia Borane with Mechanically Activated Hexagonal Boron Nitride." Journal of Physical Chemistry C 113(3):1098-1103.  doi:10.1021/jp8087385
  • Pons V, RT Baker, NK Szymczak, DJ Heldebrant, JC Linehan, MH Matus, DJ Grant, and DA Dixon. 2009. "Coordination of aminoborane, NH2BH2, dictates selectivity and extent of H2 release in metal-catalysed ammonia borane dehydrogenation." Chemical Communications 48: 6597-6599.  doi:10.1039/b809190k

2008

  • Heldebrant DJ, AJ Karkamkar, JC Linehan, and T Autrey. 2008. "Synthesis of Ammonia Borane for Hydrogen Storage Applications." Energy & Environmental Science 1(1):156-160. 
  • Dietrich BL, KI Goldberg, DM Heinekey, T Autrey, and JC Linehan. 2008. "Iridium Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics and Implications for Hydrogen Storage." Inorganic Chemistry 47(19):8583-8585.  doi:10.1021/ic801161g
  • Fister TT, FD Vila, GT Seidler, L Svec, JC Linehan, and JO Cross. 2008. "The Local Electronic Structure of Dicarba-closo-dodecaboranes C2B10H12." Journal of the American Chemical Society 130(3):925-932.  doi:10.1021/ja074794u
  • Fister TT, GT Siedler, EL Shirley, FD Vila, KP Nagle, JJ Rehr, JC Linehan, and JO Cross. 2008. "The local electronic structure of a-Li3N ." Journal of Chemical Physics 129(4):345-352; Article No. 044702. 
  • Shaw WJ, Y Chen, JL Fulton, JC Linehan, A Gutowska, and TE Bitterwolf. 2008. "Structural Evolution of a Recoverable Rhodium Hydrogenation Catalyst." Journal of Organometallic Chemistry 693(12):2111-2118.  doi:10.1016/j.jorganchem.2008.03.011
  • Shaw WJ, JC Linehan, NK Szymczak, DJ Heldebrant, CR Yonker, DM Camaioni, RT Baker, and T Autrey. 2008. "In Situ Multinuclear NMR Spectroscopic Studies of the Thermal Decomposition of Ammonia Borane in Solution." Angewandte Chemie International Edition 47(39):7493-7496.  doi:10.1002/anie.200802100
  • Xiong Z, YS Chua, G Wu, WL Xu, P Chen, WJ Shaw, AJ Karkamkar, JC Linehan, TD Smurthwaite, and T Autrey. 2008. "Interaction of Lithium Hydride and Ammonia Borane in THF ." Chemical Communications 43:5595-5597.  doi:10.1039/b812576g
  • Zheng F, SD Rassat, DJ Heldebrant, DD Caldwell, CL Aardahl, T Autrey, JC Linehan, and KG Rappe. 2008. "Automated gas burette system for evolved hydrogen measurements." Review of Scientific Instruments 79(8):Article no: 084103.  doi:10.1063/1.2968715

2007

  • Fulton JL, JC Linehan, T Autrey, M Balasubramanian, Y Chen, and NK Szymczak. 2007. "When is a Nanoparticle a Cluster? An Operando EXAFS Study of Amine Borane Dehydrocoupling by Rh4-6 Clusters." Journal of the American Chemical Society 129(39):11936-11949.  doi:10.1021/ja073331
  • Stowe AC, WJ Shaw, JC Linehan, B Schmid, and T Autrey. 2007. "In situ solid state B-11 MAS-NMR studies of the thermal decomposition of ammonia borane: mechanistic studies of the hydrogen release pathways from a solid state hydrogen storage material." Physical Chemistry Chemical Physics. PCCP 9(15):1831-1836.  doi:10.1039/b617781f

2006

  • DuBois DL, DM Blake, A Miedaner, CJ Curtis, MR DuBois, JA Franz, and JC Linehan. 2006. "Hydride Transfer from Rhodium Complexes to Triethylborane." Organometallics 25(18):4414-4419.  doi:10.1021/om060584z
  • Linehan JC, CM Stiff, and GE Fryxell. 2006. "A simple determination of alkylsilane monolayer population density." Inorganic Chemistry Communications 9(2):239-241. 
  • Brown C, T Jacques, NJ Hess, LL Daemen, E Mamontov, JC Linehan, AC Stowe, and T Autrey. 2006. "Dynamics of Ammonia Borane Using Neutron Scattering." Physica B Condensed Matter 385(Pt.1 ):266-268. 
  • Fulton JL, DW Matson, KH Pecher, JE Amonette, and JC Linehan. 2006. "Metal-based Nanoparticle Synthesis from the Rapid Expansion of Carbon Dioxide Solutions." Journal of Nanoscience and Nanotechnology 6(2):562-567. 

2005

  • Chen Y, JL Fulton, JC Linehan, and T Autrey. 2005. "In-situ XAFS and NMR Study of Rhodium Catalyzed Dehydrogenation of Dimethylamine Borane. ." Journal of the American Chemical Society 127(10):3254-3255.  doi:10.1021/ja0437050
  • Gutowska A, L Li, Y Shin, CM Wang, XS Li, JC Linehan, RS Smith, BD Kay, BA Schmid, WJ Shaw, MS Gutowski, and T Autrey. 2005. "Nano-Scaffold Mediates Hydrogen Release and Reactivity of Ammonia Borane." Angewandte Chemie International Edition 44(23):3578-3582. 
  • Nurmi JT, PG Tratnyek, V Sarathy, DR Baer, JE Amonette, KH Pecher, CM Wang, JC Linehan, DW Matson, RL Penn, and MD Driessen. 2005. "Characterization and Properties of Metallic Iron Nanoparticles: Spectroscopy, Electrochemistry, and Kinetics." Environmental Science and Technology 39(5):1221-1230. 
  • Shaw WJ, JC Linehan, A Gutowska, DJ Newell, TE Bitterwolf, JL Fulton, Y Chen, and CF Windisch, JR. 2005. "Synthesis and Characterization of a Recoverable Rhodium Catalyst with a Stimulus Sensitive Polymer Ligand." Inorganic Chemistry Communications 8(10):894-896. 
  • Yonker CR, and JC Linehan. 2005. "The Use of Supercritical Fluids as Solvents for NMR Spectroscopy." Progress in Nuclear Magnetic Resonance Spectroscopy 47(1-2):95-109. 

2004

  • Bitterwolf TE, JD Newell, CT Carver, RS Addleman, JC Linehan, and GE Fryxell. 2004. "Rhodium catalysts bound to functionalized mesoporous silica." Inorganica Chimica Acta 357(10):3001-3006. 
  • Franz JA, DS Kolwaite, JC Linehan, and E Rosenberg. 2004. "Comparison of Hydrogen Atom Abstraction Rates of Terminal and Bridging Hydrides in Triosmium Clusters: Absolute Abstraction Rate Constants for Benzyl Radical." Organometallics 23(3):441-445. 
  • Franz JA, JC Birnbaum, DS Kolwaite, JC Linehan, DM Camaioni, and M Dupuis. 2004. "Activation of the Sulfhydryl Group by Mo Centers: Kinetics of Reaction of Benzyl Radical with a Binuclear Mo(mu-SH)Mo Complex and with Arene and Alkane Thiols." Journal of the American Chemical Society 126(21):6680-6691. 
  • Fryxell GE, H Wu, Y Lin, WJ Shaw, JC Birnbaum, JC Linehan, Z Nie, KM Kemner, and S Kelly. 2004. "Lanthanide Selective Sorbents: Self-Assembled Monolayers on Mesoporous Supports (SAMMS) ." Journal of Materials Chemistry 14(22):3356-3363. 
  • Fryxell GE, H Wu, Y Lin, WJ Shaw, JC Birnbaum, JC Linehan, Z Nie, KM Kemner, and S Kelly. 2004. "Lanthanide Selective Sorbents: Self-Assembled Monolayers on Mesoporous Supports (SAMMS)." Journal of Materials Chemistry 14(22):3356-3363. 
  • Yonker CR, and JC Linehan. 2004. "A High-Pressure NMR Investigation of Reaction Chemistries in a Simple Salt Hydrate." Journal of Supercritical Fluids 29(3):257-263. 

2002

  • Yonker CR, and JC Linehan. 2002. "Investigation of the Hydroformylation of Ethylene in Liquid Carbon Dioxide." Journal of Organometallic Chemistry 650((1-2)):249-257. 

2001

  • Linehan JC, CR Yonker, RS Addleman, T Autrey, JT Bays, TE Bitterwolf, and JL Daschbach. 2001. "Solvent Study of the Kinetics of Molybdenum Radical Self-Termination." Organometallics 20(3):401-407. 
  • Bitterwolf TE, DL Klein, JC Linehan, CR Yonker, and RS Addleman. 2001. "Photochemical Carbonylation of Ethane Under Supercritical Conditions." Angewandte Chemie International Edition 40(14):2692-2694. 

2000

  • Franz JA, DM Camaioni, T Autrey, JC Linehan, and MS Alnajjar. 2000. "Measurement of Select Radical Processes in Hydrocarbon Pyrolysis." Journal of Analytical and Applied Pyrolysis 54(1-2):37-64. 

1999

  • Linehan JC, CR Yonker, JT Bays, T Autrey, TE Bitterwolf, and S Gallagher. 1999. "A Kinetic Study of the Thermal Loss of Ethylene from CpNb(CO)(3)(eta(2)-C2H4) in Supercritical Fluid Solvents." Journal of the American Chemical Society 120(23):5826-5827. 
  • Autrey T, JC Linehan, LE Kaune, TR Powers, EF Mcmillan, CJ Stearns, and JA Franz. 1999. "FeS Assisted Scission of Strong Bonds in Phenoxydiphenylmethanes. Competition between Hydrogen Atom Transfer and Free Radical Rearrangement Pathways." Energy and Fuels 13(4):927-933. 
  • Darab JG, JC Linehan, and BP McGrail. 1999. "NMR characterization of simulated Hanford low-activity waste glasses and its use in understanding waste form chemical durability." In Scientific Basis For Nuclear Waste Management XXII, Materials Research Society Symposium Procedings, vol. 556, pp. 337-344.  Materials Research Society, Warrendale. 
  • Franz JA, JC Linehan, JC Birnbaum, KL Hicks, and MS Alnajjar. 1999. "Absolute Rate Expressions for Hydrogen Atom Abstraction from Molybdenum Hydrides by Carbon-Centered Radicals." Journal of the American Chemical Society 121:9824-9830. 
  • Yonker CR, JC Linehan, and JL Fulton. 1999. "The Use of High-Pressure NMR for the Determination of Phase-Behavior for Select Binary Solvent Systems." Journal of Supercritical Fluids 14(1):9-16. 
  • Yonker CR, JC Linehan, and JL Fulton. 1999. "UV, EPR, X-ray and Related Spectroscopie Techniques." Chapter 3.3 in Chemical Synthesis Using Supercritical fluids, ed. Philip G. Jessop and Walter Leitner, pp. 195-212.  Wiley-VCH, Weinheim, Germany. 

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