February 15, 2024
Journal Article

Impact of lowering potassium contamination in liquid scintillation cocktails for ultra-sensitive radiation detection

Abstract

Intrinsic 40K radioactive backgrounds from impurities of natK in liquid scintillation cocktails have been demonstrated to limit their use in ultra-sensitive applications. This work explores two methodologies for the reduction of 40K backgrounds in the cocktails, and lays the groundwork for use in ultra-sensitive applications. Alternative low-K components for the production of liquid scintillation cocktails were identified, and a simple purification method for single components and finished cocktails was developed. Both methods were verified via ICP-MS analysis. Liquid scintillation counting of selected purified cocktails demonstrated background reduction, improved stability, and enhanced performance. The best performing purified cocktail was also counted on a custom-built ultra-low background liquid scintillation counter, with results below the detector background.

Published: February 15, 2024

Citation

Rocco N.D., I.J. Arnquist, H.O. Back, M. Bliss, M. Bronikowski, M. di Vacri, and E.R. Edwards, et al. 2023. Impact of lowering potassium contamination in liquid scintillation cocktails for ultra-sensitive radiation detection. Journal of Radioanalytical and Nuclear Chemistry 332, no. 10:4223–422. PNNL-SA-185642. doi:10.1007/s10967-023-09105-x