Two different nickelate phases spontaneously form during oxygen-plasma-assisted molecular beam epitaxy deposition.

Controlled synthesis and processing allow researchers to test how ions move through energy-relevant materials.

The structure-directing agent directly interacts with framework components during material formation.

A nanosized metal catalyst directly bonded to a metal-organic framework is active in converting carbon dioxide to methanol.

Researchers developed a new tool that combines artificial intelligence and microscopy data to rapidly test new materials for fusion reactor use.

Artificial structuring in carefully designed (SrNiO3)1/(LaFeO3)n superlattices stabilized Ni4+ cations that would otherwise be unstable

Changing the environment of proteins directs their assembly into different types of larger structures.

This research addresses two topics that are not well understood in literature: the interplay between organic linkers and substrates during MOF crystallization, as well as the mechanisms that control heterostructure formation in solutions.

Researchers found that certain oxide interface configurations remain stable in extreme environments, suggesting ways to build better performing, more reliable devices for fuel cells, space-based electronics, and nuclear energy.

Performing nuclear safeguards work safely and developing the next generation workforce are complementary goals of a longstanding program sponsored by the National Nuclear Security Administration’s Office of International Nuclear Safeguards.

Scientists at PNNL's Center for Molecular Electrocatalysis (CME) are working to understand the fundamental reactivity of H2 that could contribute to making hydrogen a more widely used fuel source.

Using a bio-inspired design that mimics nature's catalysts-enzymes, researchers at PNNL have designed a rarely seen reversible synthetic catalyst.

At PNNL, scientists have mapped the reaction that turns wind-generated electricity into fuel and the amount of energy needed for each step.

Dr. Morris Bullock and Dr. Monte Helm reviewed the catalysis research at the Center for Molecular Electrocatalysis, where Bullock is the director, in a recent article in Accounts of Chemical Research.

Generating power without gasoline, diesel, or coal could change our nation's energy and security landscape. However, replacing technologies that use fossil fuel with ones that require rare metals is unsustainable.

Making hydrogen economically demands a quick, efficient reaction. Creating that reaction demands a catalyst. CME scientists found that a proton and water-packed environment lets the catalyst work 50 times faster—without added energy.

Quickly, reliably turning wind energy into fuel means looking beyond the catalyst to its foundation, according to a recent study from the Center for Molecular Electrocatalysis.

At PNNL, scientists have elaborated on a strategy to map the catalytic route. Scientists can now explore design decisions with molecular catalysts that store or release energy from the chemical bond in dihydrogen (H2).

In an invited ACS Catalysis Viewpoint paper, scientists at PNNL proposed a way to measure and report the energy efficiency of molecular electrocatalysts.